Combustion and emissions characteristics of compression-ignition engine using dual ammonia-diesel fuel

Abstract

This study investigated the combustion and emissions characteristics of a compression-ignition engine using a dual-fuel approach with ammonia and diesel fuel. Ammonia can be regarded as a hydrogen carrier and used as a fuel, and its combustion does not produce carbon dioxide. In this study, ammonia vapor was introduced into the intake manifold and diesel fuel was injected into the cylinder to initiate combustion. The test engine was a four-cylinder, turbocharged diesel engine with slight modifications to the intake manifold for ammonia induction. An ammonia fueling system was developed, and various combinations of ammonia and diesel fuel were successfully tested. One scheme was to use different combinations of ammonia and diesel fuel to achieve a constant engine power. The other was to use a small quantity of diesel fuel and vary the amount of ammonia to achieve variable engine power. Under the constant engine power operation, in order to achieve favorable fuel efficiency, the preferred operation range was to use 40–60% energy provided by diesel fuel in conjunction with 60–40% energy supplied by ammonia. Exhaust carbon monoxide and hydrocarbon emissions using the dual-fuel approach were generally higher than those of using pure diesel fuel to achieve the same power output, while NO x emissions varied with different fueling combinations. NO x emissions could be reduced if ammonia accounted for less than 40% of the total fuel energy due to the lower combustion temperature resulting in lower thermal NO x . If ammonia accounted for the majority of the fuel energy, NO x emissions increased significantly due to the fuel-bound nitrogen. On the other hand, soot emissions could be reduced significantly if a significant amount of ammonia was used due to the lack of carbon present in the combination of fuels. Despite the overall high ammonia conversion efficiency (nearly 100%), exhaust ammonia emissions ranged from 1000 to 3000 ppmV and further after-treatment will be required due to health concerns. On the other hand, the variable engine power operation resulted in relatively poor fuel efficiency and high exhaust ammonia emissions due to the lack of diesel energy to initiate effective combustion of the lean ammonia-air mixture. The in-cylinder pressure history was also analyzed, and results indicated that ignition delay increased with increasing amounts of ammonia due to its high resistance to autoignition. The peak cylinder pressure also decreased because of the lower combustion temperature of ammonia. It is recommended that further combustion optimization using direct ammonia/diesel injection strategies be performed to increase the combustion efficiency and reduce exhaust ammonia emissions.