Abstract
The reaction between (η5-C5H4I)Fe(CO)2CH3 (2) and 2,5-bis[(trimethylstannyl)ethynyl]thiophene in the presence of palladium affords the iron which upon treatment with I2 is transformed to the corresponding (5). Reaction of the latter, in the presence of palladium, with the (trimethylstannyl)acetylide MLn = W(CO)3CH3, 9b, MLn = Re(CO)3) affords the polymetallaacetylide (10, MLn = W(CO)3CH3; 11, MLn = Re(CO)3). Trimethyltin derivatives of poly(ethynylthiophene) oligomers have been also prepared and tested for their use as spacers in poly(metallaacetylide) complexes.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
