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Combined contamination of OPEs and PAEs in coastal sediments: Distribution, sources, and ecological risks in Northern China's Marginal Seas.

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Combined contamination of OPEs and PAEs in coastal sediments: Distribution, sources, and ecological risks in Northern China's Marginal Seas.

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Probabilistic ecological risk assessment of cadmium in the Bohai Sea using native saltwater species
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  • Jingli Mu + 4 more

Predicted no-effect concentration (PNEC) is often used in ecological risk assessment to determine low-risk concentrations for chemicals. In the present study, the chronic data from native saltwater species were used to calculated PNEC values using four methods: log-normal distribution (ETX 2.0), log-triangle distribution (US EPA’s water quality criteria procedure), burr III distribution (BurrliOZ) and traditional assessment factor (AF). The PNECs that were calculated using four methods ranged from 0.08 μg/L to 1.8 μg/L. Three of the SSD-derived PNECs range from 0.94 to 1.8 μg/L, about a factor of two apart. To demonstrate the use of SSD-based PNEC values and comprehensively estimate the regional ecological risk for cadmium in surface water of the Bohai Sea, in the Liaodong Bay, Bohai Bay, and Laizhou Bay, China, the dissolved cadmium concentrations were measured and obtained 753 valid data covering 190 stations from July 2006 to November 2007. Based on three ecological risk assessment approaches, namely hazard quotient (HQ), probabilistic risk quotient and joint probability curve (JPC), the potential ecological risk of cadmium in surface water of the Liaodong Bay, Bohai Bay, and Laizahou Bay were estimated. Overall, the ecological risk of cadmium to aquatic ecosystem in the whole Bohai Sea was at acceptable ecological risk level, the order of ecological risk was Liaodong Bay>Bohai Bay>Laizhou Bay. However, more concerns should be paid to aquatic ecological risk in the Liaodong Bay which is the home of many steel, metallurgy and petrochemical industrial in China.

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Comprehensive profiling of quinolone antibiotics in the Bohai Sea: Occurrence, source apportionment, and environmental risks.
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A numerical study of the effects of coastal geometry in the Bohai Sea on storm surges induced by cold-air outbreaks
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Strom surges are not only determined by the atmospheric forcing, but also influenced by the coastal geometry and bathymetry. The Bohai Sea, as one of China’s marginal seas, is seriously harmed by storm surges, especially those caused by cold-air outbreaks. As the coastline of the Bohai Sea has changed evidently these years, storm surges may have new characteristics due to the changes in the local geometry. This paper aims to find out these new characteristics by primarily investigating the influence of the changes in the local geometry on storm surges with numerical methods. 20 scenarios were constructed based on the track and intensity of the cold-air outbreaks to describe the actual situation. By analyzing the model results of the control scenarios, it is found that the main changes of the maximum surge elevation occur in the Bohai Bay and the Laizhou Bay. At the top of the Bohai Bay, the maximum surge elevation is obviously decreased, while in the Laizhou Bay, it is enhanced by the growing Yellow River Delta. This, however, does not suggest that the storm surges in the Laizhou Bay become more serious. A comparison of the risk assessment of storm surges in the Tanggu, Huanghua and Yangjiaogou regions shows that the risk of storm surges in these coastal areas is lightened by the evolvement of the coastal geometry. Particularly near Yangjiaogou, though the maximum surge elevation becomes higher to subject more areas to risk, the risk is still reduced by the evolvement of the Yellow River Delta.

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Flux and source-sink relationship of heavy metals and arsenic in the Bohai Sea, China
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  • Jan 1, 2024
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Since the 1970s, extensive land reclamation has been carried out in the Bohai Sea. However, reclamation activities were prohibited in 2018. Using the MIKE3 numerical model, this study selected 1976 and 2018 as representative years before and after reclamation, respectively, and developed a highly accurate three‐dimensional hydrodynamic and sediment transport model for the Bohai Sea. The model was employed to access the effects of reclamation on tidal waves, tidal prism, residual current, tidal flux (TF), and suspended sediment flux (SSF). The results revealed that after reclamation, the amphidromic points of M2 and S2 shifted southward near Qinhuangdao, and eastward near the Yellow River estuary. The M2 amplitude in the Bohai Bay exhibited a maximum increase of 30 cm. In the Bohai Sea, the tidal prism decreased by 3.95%, suggesting a decrease in water exchange capacity. The TF in the Bohai Sea and Laizhou Bay decreased by 0.7% and 12%, respectively, while increasing by 16% in Bohai Bay and 12% in Liaodong Bay, primarily due to the variations in tidal waves. Furthermore, SSF decreased by 6% in the Bohai Sea, but increased by 125% in Bohai Bay and 114% in Laizhou Bay. The significant increase in SSF in Bohai Bay and Laizhou Bay was mainly attributed to the higher suspended sediment concentrations and the stronger residual current velocities near the Yellow River estuary. This study provides comprehensive insights into the impacts of reclamation on TF and SSF in the Bohai Sea, which could contribute to marine resource development and the planning of environmental restoration projects.

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Roadside soils are regarded as a reservoir for heavy metal pollution, which potentially leads to ecosystem deterioration as well as serious hazard to human health. A comprehensive investigation was conducted for the levels, relationship with soil properties, and potential sources of heavy metals (Hg, Cu, Zn, Pb, Cd, and Cr) in roadside soils in six cities (Changzhi, Jincheng, Yuncheng, Linfen, Xinzhou, Datong) of Shanxi Province; and the corresponding ecological risk and human health risk associated with the concentrations of heavy metals were addressed. Heavy metal concentrations of 112 roadside soil samples in the surveyed cities were, in decreasing order, Zn, Cu, Cr, Pb, Cd, and Hg, which were higher than corresponding background values. The highest concentrations were in Changzhi. The results of Pearson correlation analysis demonstrated that positive correlations in varying degrees existed between soil properties such as electrical conductivity, total nitrogen, total phosphorus, and total organic carbon with specific heavy metals and that negative correlations were observed for clay and electrical conductivity. Anthropogenic sources related to traffic emissions and industrialization were the main sources of heavy metals in roadside soils according to principal component analysis. The ecological risk assessments were achieved by pollution index and potential risk index, indicating that contamination with Hg was the most serious, which posed the highest risk to the ecosystems in the surveyed cities; and the ecological risk in Changzhi ranked at the top compared with other cities. For the human health risk assessment, the results demonstrated that the noncarcinogenic and carcinogenic risks were in the acceptable range in the surveyed cities. However, there was a higher health risk from heavy metal exposure for children than adults, and the main exposure pathway was soil ingestion. In addition, Changzhi was the city with the highest noncarcinogenic and carcinogenic risks, and the main human health risks were posed by Cr contamination in roadside soil, which was different from the results of ecological risks. Both results of ecological and health risk assessment demonstrated that the higher risk exhibited in southern and southeastern cities than northern cities in Shanxi Province. Environ Toxicol Chem 2023;42:1485-1500. © 2023 SETAC.

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Contamination status, partitioning behavior, ecological risks assessment of legacy and emerging per- and polyfluoroalkyl substances in a typical heavily polluted semi-enclosed bay, China

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