Abstract
We investigate collisional line-shape effects that are present in highly accurate experimental spectra of the 3-0 S(1) and 2-0 Q(1) molecular hydrogen absorption lines perturbed by helium. We clearly distinguish the influence of six different collisional effects (i.e.: collisional broadening and shift, their speed dependencies and the complex Dicke effect) on the shapes of H2 lines. We demonstrate that only a very specific combination of these six contributions, determined from our ab initio calculations, gives unprecedentedly good agreement with experimental spectra. If any of the six contributions is neglected, then the experiment-theory comparison deteriorates at least several times. We also analyze the influence of the centrifugal distortion on our ab initio calculations and we demonstrate that the inclusion of this effect slightly improves the agreement with the experimental spectra.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Journal of Quantitative Spectroscopy and Radiative Transfer
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.