Abstract

Abstract A collaborative study was made of an automated method for total and direct available phosphorus (P2O5) in comparison with the official gravimetric quimociac method, 2.023–2.025. Eight laboratories participated in the analysis of the 13 sample solutions, and the results were evaluated by the technique of closely matched pairs. The fc-test showed no difference in the means of the results of the 2 methods. The estimates of the random, systematic, and total errors of the automated method all differed significantly from those of the official method when evaluated by the F-test. Further study of the automated method for P2O5 in fertilizers is recommended.

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