Abstract
Two metal coordination polymers, namely {[Co(1,3-BIP)(OBA)]·0.5H2O}n (SNUT-1) and [Co2(µ-η1:η1-O2)(1,3-BIP)2(PMA)]n (SNUT-2), where 1,3-BIP = 1,3-bis(imidazol)propane, H2OBA = 4,4′-oxybis(benzoate) and H4PMA = benzene-1,2,4,5-tetracarboxylic acid, were prepared by hydrothermal methods. Single-crystal X-ray analysis revealed that the structure of SNUT-1 consists of a 3D → 3D twofold interpenetrating network that can be described as a 4-connected uninodal net with (65·8) topology. The structure of SNUT-2 consists of a 3D framework which can be described as a (4,5)-connected binodal net with (42·63·84·10) (33·42·5) topology. The gas adsorption properties of SNUT-1 and photocatalytic activity of SNUT-2 for the degradation of Rhodamine B have been explored.
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