Coal rank variations with depth related to major thrust detachments in the South Wales coalfield: implications for fluid flow and mineralization

Abstract

Abstract Coal maturity data in the form of volatile matter (daf and dmmf) and random vitrinite reflectance have been analysed for the South Wales coalfield. They show that in general coals increase in rank with depth, obeying Hilt’s law, and increase in rank laterally from high volatile bituminous coals in the south and east of the coalfield to anthracite in the northwest of the coalfield. The lateral increase in rank does not coincide with the basin depocentre which was located to the southwest of the coal basin during Westphalian times. The rank pattern with depth in the Westphalian A-Lower Westphalian C Coal Measures of the eastern half of the coalfield suggests a palaeogeothermal gradient of approx. 310°C km −1 , equivalent to a basal heatflow of 295 m Wm −2 . Investigation of vitrinite reflectance in a coal sequence repeated by intense Variscan thrusting indicates that coal rank was acquired both pre- and syn-thrusting. Detailed analysis of the volatile matter data reveals the presence of excursions from Hilt’s law present in one or more coal seams close to the boundary between Westphalian A & B. Of the 154 data sets analysed from the coalfield, 94 (61%) show one or more excursion. It is shown that the excursions correlate with thrust detachments within the coal seams, and it is argued that the excursions represent an increase in maturity temperature caused by fluids carrying heat into the coal seam along the seismically active thrusts. The fluids may also have been responsible for the carbonate, oxide and sulphide mineralization of the coalfield. Preliminary comparisons with the Ruhr coal basin in Germany suggest that future studies involving computer generated thermal models are required to understand the thermal evolution of both basins.