Abstract
{Pd[C 6 H 4 C(Me)=NNPh][P(OMe) 3 ]}, C 34 H 42 N 4 O 6 P 2 Pd 2 , cristallise dans P2 1 /n avec a=13,477, b=19,546, c=14,231 A, β=97,43˚, Z=4; affinement jusqu'a R=0,057. Le cycle Pd 2 N 4 a une forme de papillon, avec une charniere le long des atomes N sans proton et une distance Pd-Pd de 3,788 A. Outre ce compose, d'autres complexes du palladium ont ete synthetises et la tendance a la coordination ou non de l'atome libre de l'amine etudiee
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