Abstract
The title compound, cis-[Pd2Cl3(C7H7S)(C6H15P)2], has bridging chloro and arylthiolato groups, with the phosphines being trans to the bridging chloro group. The four-membered metallocyclic Pd2ClS ring is unexpectedly non-planar, with a dihedral angle of 133.8 (1)° between the PdCl2SP coordination planes. Principal dimensions include Pd—Clt 2.316 (3) and 2.329 (3), Pd—Clb 2.442 (3) and 2.432 (3), Pd—S 2.280 (3) and 2.282 (3), and Pd—P 2.233 (3) and 2.236 (3) A (where Clt and Clb are terminal and bridging chloro ligands, respectively).
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