Abstract
The effect of a mobile phase polyvalent counter ion on the retention behavior and peak intensity of sulfate in non- suppressed ion chromatography was quantitatively studied using a chromatogram simulation method. In this study, both indirect photometric detection (IPD) method and conductometric detection (CD) method were evaluated. With the IPD method, the retention of sulfate was observed to decrease in the presence of the polyvalent counter ion (Trien) without any change in peak intensity. With the CD method, however, peak intensity of sulfate decreased and, under some conditions, gave a negative peak in simulation as was also observed in actual experiments. The present work demonstrates the possibility of predicting the effect of a polyvalent counter ion on sulfate retention without resorting to physical experiments.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
