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Abstract
Chromatographic retention indices on a standard nonpolar poly(dimethylsiloxane) phase were determined for 33 α-alkynols and their 27 dehydration products (conjugated alkenynes). The resulting data are proposed to be verified using the retention indices of acetylenic alcohols estimated by the additive scheme from the retention indices of isostructural alkynes with the inclusion of increments for secondary and tertiary hydroxy groups. The analogous approach to data the verification of data for alkenynes is based on correlation of their retention indices with normal boiling points.
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