Chlorine in basalts from Iceland

Abstract

Chlorine has a higher solubility in basaltic magmas than other volatiles. A theoretical degassing model predicts that less than 10% of the chlorine originally present in the magma is lost to the atmosphere during surface degassing. This prediction is born out by strong correlation between chlorine and nonvolatile elements in samples from recent volcanic eruptions in Iceland. It is concluded that the chlorine content of subaerial basaltic lavas is proportional to the chlorine content of the magmas. Assuming a roughly constant ratio between chlorine and water in the magmatic gas phase and assuming further that this ratio approximates the Cl H 2O ratio in sea water and sediments it is possible to assign each basaltic magma a fixed amount of water. The figures thus obtained (0.3–1.2% H 2O) are identical with previously assumed water contents of basaltic magmas. The implied water contents of the melts are discussed in terms of derivation from hydrous mantle phases. It is concluded that such phases can supply only a fraction of the assumed water content, the rest is derived from an additional volatile source in the mantle. The mantle source giving rise to alkali basalts in Iceland has a lower content of volatiles than the tholeiite source.