Abstract
Many new boryl-substituted organic, main group, and organometallic compounds have been synthesized and characterized. This chapter focuses on the preparative methods of boryl anion derivatives having boron-metal bonds and nucleophilicity on the boron atom. It describes a preparation of boryl anions as a salt with alkali metal cations. The chapter summarizes preparative methods for a series of boryl anions with other metals such as magnesium, copper, and zinc, as the family of carbanions has these metals. Borylcopper and borylzinc species were applied to synthetic organic chemistry to prepare boron-containing compounds. All the available methods to prepare boryl anions were classified into several types depending on the substituents and counter cations. In addition to boryl anions, the chemistry of group 13 element anions, such as of aluminium, gallium, and indium, is expanding. Mixing these group 13-element anions with electrophiles would provide a wide range of molecules containing group 13 elements with new bonding, structure, and functions.
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