Abstract

4-Oxoalkane-1,1,2,2-tetracarbonitriles are products of addition of tetracyanoethylene to ketones. Their molecules possess several electrophilic centers capable of reacting with nucleophiles. However, studies on reactions of these compounds with nitrogen-centered nucleophiles are very few in number. It was reported that reactions of 4-oxoalkane-1,1,2,2-tetracarbonitriles with aqueous ammonia lead to formation of isonicotinic acid derivatives [1] and 2,7-diazabicyclo[3.2.1]oct-3-enes [2].

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