Abstract

Abstract(‐)‐Isopulegol undergoes Prins‐arylthiolation with aldehydes and cyclohexanone in the presence of HBF4·OEt2 to generate a library of 4‐arylthio‐octahydro‐2H‐chromene derivatives in good to excellent yields with moderate to high cis selectivity at ambient temperature in CH2Cl2.

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