Abstract
Photodissociation of Co(CO) 3 (NO), Co(CO) 2 (NO)(PMe 3 ), and Co(CO) 2 (NO)(PEt 3 ) in the visible region (450-497 nm) is investigated by probing the ro-vibrational distribution of the nitric oxide fragments. The NO distribution is monitored via [2+2] resonantly enhanced multiphoton ionization (REMPI). Co(CO) 3 (NO) produces NO over the υ=0-2 vibrational levels, while the phosphine-substituted derivatives form NO almost exclusively in the υ=0 level. The rotational structure of the (0,0) REMPI band is found to be very similar for all cobalt compounds studied here, and similar to that observed in a previous study of (η 5 -C 5 H 50 )NiNO
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