Abstract

Carbonyl compounds 1 were converted to the corresponding 1,3-dioxolanes 2 and 1,3-dioxanes 4 with ethylene glucol and 2,2-dimethyl-1,3-propandiol, respectively, in the presence of 1-3 mol% of N-(benzyl, 4-methylbenzyl or 4-methoxybenzyl)-2 (or -4)-cyanopyridinium hexafluoroantimonates 3. The catalyst 3d was also effective for the tetrahydropyranylation

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