Abstract
Manganese(II) tetraphenylporphyrin, MnII (tpp) (tpp = meso-tetraphenylporphinato), was afforded by the pyrolysis of MnIV(tpp)(OCH3)2 at ≈180 °C under 10−4–10−5 Torr (1 Torr ≅ 133.3 Pa). The pyrolysis of MoVO(tpp)OR (R = CH3, C2H5) in the solid state yielded MoIVO(tpp).
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