Abstract
The photochemical behaviour of cis and trans 1,2-bis(2-bromo-3-thienyl)ethene has been separately studied with respect to cyclization to benzo[2,1-b:3,4-b′]dithiophene (BDT). The gc/ms analysis of the mother liquors of the two isomers photoreaction shows the opposite direction of isomerization followed by production of intractable materials resulting by the radical breaking of one of the two C-Br bonds on the thiophene moiety. On the contrary, in EI mass spectrometry both the isomers give rise to fragment ions at m/z 190 studied and compared to BDT with the aid of mass analysed ion kinetic energy spectrometry and collisional spectroscopy.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
