Abstract
Doped poly(1-alkyl 2,5-pyrrolylenes) (alkyl= hexyl and dodecyl) are synthesized by oxidative coupling of the corresponding N-alkyl pyrroles in nitromethane using excess FeCl 3 as the oxidant. The electrical conductivities of the doped polymers let al,in the range. 10 −5 to 10 −6 S/cm. The doped polymers are stable in air. Rationalizations are presented for conductivity in relation to polymer structure.
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