Chemical characterization of the long-range transport of firework/firecracker emissions over the Korean Peninsula: A novel indicator of Asian continental outflows

Abstract

The long-range transport (LRT) of pollutants between countries in Northeast Asia is a serious issue. However, reliable quantification of LRT pollutants has not been performed due to a lack of clear evidence of the transport between countries. Hourly chemical composition of PM2.5 (particulate matter with a diameter of ≤2.5 μm) was measured continuously at a suburban site in Daejeon, Korea during the Lunar New Year festival period to investigate the influence of firework/firecracker emissions from China over areas downwind subject to LRT. Elevated PM10 (particulate matter with a diameter of ≤10 μm) and PM2.5 mass concentrations were observed over the Korean Peninsula during the third day of the Lunar New Year festival (30 January 2017) when air masses originated from the northern part of China. Water-soluble potassium (K+), an indicator of both firework/firecracker and biomass burning, increased significantly during the third day of the Lunar New Year festival with an episode to non-episode ratio of 7.5, whereas no increase in levoglucosan, an indicator of biomass burning, was observed. Because firework/firecracker activities do not typically occur over the Korean Peninsula during the Lunar New Year festival, elevated K+ indicates that haze plumes mixed with firework/firecracker emissions in China impacted the Korean Peninsula through the LRT. This study finds, for the first time, clear evidence of the LRT of pollutants between source and receptor countries in Northeast Asia under Asian continental outflow.