Abstract

Copper immersed in a 0.025 M Na 2S 4 solution at pH 11 turns black at a characteristic time that is controlled by the presence of films or contaminants on the copper surface. The color change occurs coincident with an abrupt change in the corrosion potential. It is hypothesized that the rate-controlling step is the conversion of elemental copper and/or copper (I) to the copper(II) valence state. The rate of this reaction is controlled by the chemical nature of the copper surface. The procedure shows promise for characterizing the cleanliness of copper surfaces.

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