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Characterization of zirconia sulfate catalyst for sustainable aviation fuel from waste cooking oil

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Abstract
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In 2022, the amount of Waste Cooking Oil (WCO) in the Java–Bali region was estimated to reach 207 million kiloliters. This poses a significant environmental challenge due to the lack of proper utilization. With the increasing demand for cooking oil in Indonesia, the generation of WCO continues to rise. Low-quality WCO, often traded by street vendors, cannot be reused and must be discarded. Improper disposal into drainage systems leads to long-term problems such as water pollution, soil degradation, greenhouse gas emissions, and contamination of clean water sources. The development of Co/ZrO₂–SO₄ catalysts and optimized conversion processes plays a crucial role in reducing reliance on imported catalysts, particularly for the production of environmentally friendly fuels (green fuels) such as bio-jet fuel. Given the high fatty acid content in WCO, several pretreatment stages are required. This study aims to convert WCO into bio-jet fuel through hydrodeoxygenation and Pyrolytic Catalytic Cracking (PCC) accompanied by isomerization. The PCC process was carried out under atmospheric pressure and relatively mild temperatures. The Co/ZrO₂–SO₄ catalyst was employed to enhance conversion into bio-jet fuel products. In this work, cobalt-dispersed sulfated zirconia nanocatalysts (Co/SZ) were synthesized with varying cobalt loadings (1%, 3%, and 5%). Beyond hydrodeoxygenation and cracking, the catalyst was also applied in the isomerization process. The synthesized catalysts were characterized using FTIR, XRD, SEM, and NH₃-TPD. Meanwhile, the cracking process was conducted at different reactor temperatures (400, 450, 500, and 550 °C), with the resulting products analyzed by BET, XRF, TEM-SAED, and GC-MS.

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With an alarming increase in dumping of municipal solid waste to landfill in Hong Kong, of which food waste dominated, it is now the best opportunity to promote the use of biodiesel produced from waste cooking oils. Biodiesel has its main advantages as renewability, biodegradability, non-toxicity, non-greenhouse effect contributor and safety.
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\nIn this project, biodiesel was produced from waste cooking oils in laboratory. The feedstock used were home-used deep-frying canola oil, home-used pig oil, deep-fried oil obtained from a restaurant and fresh canola oil. Investigation and comparison were made between household waste cooking oil, restaurant cooking oil and fresh cooking oil in terms of quantity and quality by analysis on product density, cloud point, pour point and components by gas chromatography as well as mass spectrometry. 
\nWaste cooking
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Pendampingan Pembuatan Sabun Dari Limbah Minyak Goreng Di Desa Hamparan Perak
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Community service KKN Mandiri Muhammadiyah University of North Sumatra carried out one of the entrepreneurial activities for the community in Hamparan Perak Village, considering the large amount of waste cooking oil in the community environment that was simply thrown away. Soap-making training activities are needed so that the community can set an example and apply the business of making soap from cooking oil waste. I carried out soap training to provide knowledge and understanding about soap making from cooking oil waste so that people could have the habit of entrepreneurship. The method of activity uses the following stages: survey of the community environment, data collection, preparation of problems that occur in the community, consultation and application of licensing for program implementation to the village head and neighbourhood head; preparation of materials and preparation of methods and tools to be used; implementation of soap-making training in the hall of the village head's office in the expanse of silver.

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