Abstract
The partial thermodynamic functions of the V–N system from V to VN over the temperature range 1000 to 2100 K have been investigated. The discrepancies among the pressure–composition–temperature ( p–C–T) relationships in the δ-VN single-phase region have been resolved. The p–C–T relationships for other phases, where no data were available from the literature, have been established by applying the appropriate thermodynamic constraints and a modified form of Sieverts law. The results are presented as the nitrogen isobars superimposed on the phase diagram.
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