Abstract
Nonylphenol polyethoxylates (A9PEs) are complex mixtures of isomers and oligomers widely used as surfactants. The weakly estrogenic effects of the A9PE breakdown products are impelling reformulation of many commercial products and have made “A9PE free” products an industry trend. Initial A9PE biotransformation is known to produce metabolites with shortened ethoxy chains, mainly A9PE2, and carboxylated ethoxy chains, mainly A9PE2C. Very little is known on the ultimate fate of the branched alkyl side chain. We have used liquid chroma tography−electrospray−mass spectrometry to elucidate structures of species generated from biotransformation of the branched alkyl chain. According to an OECD protocol, a laboratory A9PE biodegradation experiment was conducted. After about two weeks from the beginning of the experiment, relevant amounts of species having both side chains oxidized (CAPECs) and 3−8 carbons in the residual alkyl chain appeared in the test solution. These species were presumably generated from less ...
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