Abstract
Two series of tetraketones, consisting of two β-diketone moieties linked through alkyl chains to form either linear or branched structures, were investigated as the parent compounds of potentially bis-chelating, dinegative ligands for metal ions. The dependence of their keto-enol and acid-ionization equilibria on the point of attachment and length of the connecting alkyl chain was established by potentiometric titration and spectroscopic techniques(infrared, ultraviolet, 1H and 13C NMR).
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