Abstract

The effects of plating conditions were investigated on the composition of Cr-Ni alloys electrodeposited on brass substrates from a chromium(III)-nickel(II) bath at 30oC. At 10 A/dm2, Ni-rich deposits were obtained, whereas and at 40 A/dm2, Cr-rich deposits were formed. Hence, pulsed-current electroplating was used to develop Cr- and Ni-rich multi- layers with a thickness modulation of tens of nanometers. Microstructures of Cr-Ni multilayers were investigated by transmission electron microscopy (TEM) and electron diffraction.

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