Abstract

In this paper we report the synthesis and luminescence of strontium cerium oxide (Sr2CeO4:Eu 3+ (0.5mol%),La 3+ (0.5mol%) prepared by solid state reaction method in air at 12000C.These samples were characterized by X-ray diffraction, scanning electron microscope (SEM) and photoluminescence (PL) techniques, particle size analysis. The photo luminescence (PL) spectra of pure and Eu 3+ , La 3+ codoped Sr2CeO4 were recorded at room temperature. Sr2CeO4 phosphor was effectively excited around 250 nm and observed a broad emission band peak around 467 nm. XRD data revealed that the structure of Sr2CeO4 is orthorhombic, and the mean crystallite size of Sr 2CeO4 and Sr2CeO4: Eu 3+ , La 3+ were 9 nm and 11nm respectively. The colour co-ordinates of Sr2CeO4 were x = 0.16 and y = 0.18 and CIE co-ordinates revealed that the present phosphors may be used in white light applications.

Highlights

  • The search for blue phosphor emitters has been increasing due to their applicability in many fields, such as cathode ray tubes, projection televisions, fluorescent tubes, X-ray detectors and field emission displays [1]

  • Sr2CeO4 crystals doped with rare-earth elements have been studied since an unusual blue phosphor Sr2CeO4 was prepared using the combinatorial techniques by Danielson et al in 1998

  • We have studied on the synthesis, size, morphology and photoluminescence properties of pure and Eu3+, La3+ codoped Sr2CeO4 phosphors prepared by solid state reaction method in air at 12000C

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Summary

Introduction

The search for blue phosphor emitters has been increasing due to their applicability in many fields, such as cathode ray tubes, projection televisions, fluorescent tubes, X-ray detectors and field emission displays [1]. His current research interest is in the synthesis and characterization of blue emitting phosphor for solid state lighting.

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