Abstract
Based on the phenomenon of soil polluted by Hexavalent chromium (Cr(VI)), this study systematically examined the efficiency, stability and feasibility of using sodium carboxymethyl cellulose-stabilized nanoscale ferrous sulfide (CMC-nFeS) to immobilize Cr(VI) in contaminated soil. The experiments described herein showed CMC-nFeS exhibited superior dispersity and a higher antioxidative effect than nFeS alone. Batch tests indicated the nanoparticles could effectively immobilize Cr(VI) in soil. At Cr(VI) concentrations of 56.01–502.21 mg/kg, the reducing capacity of CMC-nFeS was 54.68–198.74 mg Cr(VI)/g FeS. Following treatment with CMC-nFeS, the leachabilities of Cr(VI) and Crtotal determined by the Toxicity Characteristic Leaching Procedure (TCLP), Synthetic Precipitation Leaching Procedure (SPLP) and Physiologically Based Extraction Test (PBET) decreased significantly after 24 h and remained stable for 90 days. Column tests with water and simulated acid rain showed the injection of CMC-nFeS significantly increased the fixed Cr concentration and the procedure was environmentally friendly. Furthermore, analysis of the reaction mechanism demonstrated the best removal obtained in a neutral environment and Cr(VI) was reduced and immobilized in the form of Cr(OH)3 and Fe0.75Cr0.25OOH confirmed by SEM-EDS and XPS analysis.
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