Characteristics and heat treatment of cold-sprayed Al–Sn binary alloy coatings

Abstract

In this study, Al–Sn binary alloy coatings were prepared with Al–5 wt.% Sn (Al–5Sn) and Al–10 wt.% Sn (Al–10Sn) gas atomized powders by low pressure and high pressure cold spray process. The microstructure and microhardness of the coatings were characterized. To understand the coarsening of tin in the coating, the as-sprayed coatings were annealed at 150, 200, 250 and 300 °C for 1 h, respectively. The effect of annealing on microstructure and the bond strength of the coatings were investigated. The results show that Al–5Sn coating can be deposited by high pressure cold spray with nitrogen while Al–10Sn can only be deposited by low pressure cold spray with helium gas. Both Al–5Sn and Al–10Sn coatings present dense structures. The fraction of Sn in as-sprayed coatings is consistent with that in feed stock powders. The coarsening and/or migration of Sn phase in the coatings were observed when the annealing temperature exceeds 200 °C. Furthermore, the microhardness of the coatings decreased significantly at the annealing temperature of 250 °C. EDXA analysis shows that the heat treatment has no significant effect on fraction of Sn phase in Al–5Sn coatings. Bonding strength of as-sprayed Al–10Sn coating is slightly higher than that of Al–5Sn coating. Annealing at 200 °C can increase the bonding strength of Al–5Sn coatings.