Abstract
Publisher Summary This chapter discusses reactions of negative inorganic ions. Ions are grouped according to the central atom, where appropriate, or the atom undergoing most change in formal oxidation number. When a reaction involves two negative ions, there is still some ambiguity. Cross-referencing should solve some of the residual problems. The chapter reflects one of the major afflictions in kinetic studies of this type of reaction. They have proliferated without obvious interconnections. The chapter discusses the polarographic measurements at lower temperatures, and the formation of an intermediate in the reaction with carbonoxysulphide has been demonstrated. It discusses that many reactions, which formally involve nitrites in acidic solutions or in presence of a number of buffers turn out to have mechanisms in which the nitrogen oxides are dominant species. These reactions are to be discussed elsewhere. and include the decomposition of nitrous acid and its reverse, and of its reaction with arsenious acid.
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