Abstract
Homogeneous acid catalysis of nonasymmetric reactions continues to be an area of significant focus, and this chapter concentrates on recent relevant advances within a green chemistry context. The developments in acid catalysis are viewed through a number of key reactions including esterification, hydrolysis, and etherification. We begin with an overview of the typical mechanistic considerations for acid catalysis. One of the key, recent developments in the area has been a drive towards the application of novel “greener” solvent media for many classical acid-catalysed transformations. We consider the benefits offered by “green” solvents such as high temperature and supercritical water, and ionic liquids, on acid-catalysed reactions. We also briefly overview other recent advances including acid-catalysed biomass conversion and direct esterifications. Emphasis is placed throughout on the insight provided through mechanistic studies, and differences to analogous reactions in conventional aqueous media.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
