Abstract
Cobalt L-edge and oxygen K-edge X-ray Absorption Near Edge Structure (XANES) investigated change in electronic structure by electrochemical lithium ion de-intercalation in LiCoO2. The Co L-edge XANES of Li(1-x)CoO2 did not show any chemical shift even at high x value. The oxygen K-edge XANES of Li(1-x)CoO2 indicated that the holes compensating the lithium ion deintercalation are located primarily in the oxygen 2p states rather than in the Co 3d states.
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