Abstract

Suspension polymerization of styrene under ultrasonic irradiation was carried out and the change of size distribution of polymer droplets with the lapse of polymerization was measured. A stable cohesion effect of ultrasonics in the low conversion region of the monomer made the size of polymer droplets larger than those under no irradiation. However, the stable cohesion effect of ultrasonics in the high conversion region of the monomer was held even under the condition in which a caking effect takes place under no irradiation, and it made a stable operation of suspension polymerization possible.

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