Cellulose beads supported CoFe2O4: A novel heterogeneous catalyst for efficient rhodamine B degradation via advanced oxidation processes

Abstract

In this study, a novel mechanical process was used to produce cellulose beads (CB). These beads were then doped with cobalt ferrite nanoparticles (CoFe2O4 NPs) to serve as catalysts for the degradation of rhodamine B (RhB) through peroxymonosulfate (PMS) activation. The physical and chemical properties of CoFe2O4 and CoFe2O4@CB catalysts were characterized using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM) combined with energy dispersive X-ray spectrometer (EDX), scanning transmission electron microscopy (STEM) techniques, and thermogravimetric analysis (TGA). To optimize RhB degradation efficiency, Response Surface Methodology (RSM) was employed, utilizing the Box-Behnken design (BBD). Under the optimized conditions of a catalyst dosage of 0.40 g/L, PMS dosage of 0.98 mM, RhB concentration of 40 mg/L, pH of 5.27, and reaction time of 60 min, a remarkable degradation efficiency of 98.51 % was achieved at a temperature of 25 °C. In quenching experiments, 1O2, SO4•−, and HO• species are produced in the CoFe2O4@CB/PMS system, with 1O2, and SO4•− species dominating RhB degradation. Remarkably, the new CoFe2O4@CB catalyst has demonstrated exceptional stability and reusability, validated by recycling tests (up to 78 % of RhB degradation efficiency after a 5-cycle experiment) and subsequent characterizations (FTIR, SEM, and EDX) emphasizing unchanged bands, uniform distribution, and consistent composition after reuse cycles. These results demonstrate the effectiveness of mechanically produced CoFe2O4@CB catalysts for advanced oxidation processes (AOPs), with promising applications in wastewater treatment.