Cationic surfactant as a sensitizer for the spectrophotometric determination of hydrogen sulphide in air and evaluation of a new absorbing medium containing triethanolamine-zinc acetate-sodium hydroxide

Abstract

An extractive spectrophotometric method for the determination of trace amounts of hydrogen sulphide after fixing the gas in triethanolamine (TEA)-zinc acetate-sodium hydroxide solution is described. The method is based on the reaction of iodate with hydrogen sulphide in the presence of acid and excess chloride ion leading to the formation of ICl − 2 species which is used to iodinate 2′,7′-dichlorofluorescein to form 2′,7′-dichloro-4′,5′-diiodofluorescein. The iodinated product formed is extracted into an organic solvent and sensitized by equilibrating with a cationic surfactant, cetrimide, in the presence of acetate buffer (pH 5.9 ± 0.1). The colour system obeys Beer's law over the range 0–1 μg of hydrogen sulphide and the relative standard deviation is 2.4% for 10 determinations at 0.75 μg of hydrogen sulphide. The effect of interfering gases on the determination is discussed. The proposed absorbing solution has been evaluated using a hydrogen sulphide permeation device. This absorbing solution has an absorption efficiency of > 93% at a flow rate of 1.5 litre min −1 for a sampling period of 2 h. The fixed H 2S is stable for 40 days. The method has been applied to determine residual H 2S levels in a laboratory fume hood and in the vicinity of sewage pumping station. The method can be used to determine as little as 0.05 μg of hydrogen sulphide.