Abstract
The title polymer, {(C4H12N2)[Co2(C9H3O6)2(H2O)6]·2H2O}n, contains two independent CoII atoms, both of which are located on inversion centres. The benzene-1,3,5-tricarboxylate ligand bridges the CoII atoms in two coordination modes to form a one-dimensional polymeric zigzag chain structure. The zigzag chains are connected via O—H⋯O and N—H⋯O hydrogen bonds to form a three-dimensional network. This determination corrects a previous report which formulated this compound as (C4H10N2)n[C18H20Co2O18]n·2nH2O [Chen & Liu (2004). Chem. J. Chin. Univ. 25, 1189–1193].
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