Abstract
The title compound, [Ni(SO4)(C5H5N)(H2O)3]n, was synthesized by the hydrothermal reaction of NiSO4·6H2O, pyridine and water. The central NiII atom is coordinated in a distorted octahedral environment by a pyridine N atom, three aqua O atoms and two O atoms of bridging sulfate anions, yielding a zigzag chain. A three-dimensional network is generated via complex hydrogen bonds involving the sulfate and aqua ligands and a pyridine C—H group.
Highlights
Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education of China), School of Chemistry & Chemical Engineering, Guangxi Normal University, Guilin 541004, People’s Republic of China
The central NiII atom is coordinated in a distorted octahedral environment by a pyridine N atom, three aqua O
A three-dimensional network is generated via complex hydrogen bonds involving the sulfate and aqua ligands and a pyridine C—H group
Summary
Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education of China), School of Chemistry & Chemical Engineering, Guangxi Normal University, Guilin 541004, People’s Republic of China. The central NiII atom is coordinated in a distorted octahedral environment by a pyridine N atom, three aqua O atoms and two O atoms of bridging sulfate anions, yielding a zigzag chain. A three-dimensional network is generated via complex hydrogen bonds involving the sulfate and aqua ligands and a pyridine C—H group. H atoms treated by a mixture of independent and constrained refinement max = 0.57 e Å3. (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL
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