Abstract
In the title complex, {[Cu(NO3)2(C13H12N4)2]·2H2O}n, the CuII atom is located on a crystallographic center of symmetry and adopts an N4O2 octahedral coordination geometry with four imidazole N atoms in the equatorial sites and two O atoms in the axial sites. The dihedral angles between the central benzene ring and the imidazole rings are 4.93 (11) and 46.08 (12)°. The 1,3-bis(imidazol-1-yl)-5-methylbenzene ligand is bis-monodentate, linking symmetry-related CuII atoms into sheets in the bc plane. These sheets are further bridged into a three-dimensional supramolecular structure by O—H⋯O and C—H⋯O hydrogen bonds.
Highlights
In the title complex, {[Cu(NO3)2(C13H12N4)2]2H2O}n, the CuII atom is located on a crystallographic center of symmetry and adopts an N4O2 octahedral coordination geometry with four imidazole N atoms in the equatorial sites and two
The dihedral angles between the central benzene ring and the imidazole rings are 4.93 (11)
Atoms into sheets in the bc plane. These sheets are further bridged into a three-dimensional supramolecular structure by
Summary
R factor = 0.036; wR factor = 0.101; data-to-parameter ratio = 12.5. In the title complex, {[Cu(NO3)2(C13H12N4)2]2H2O}n, the CuII atom is located on a crystallographic center of symmetry and adopts an N4O2 octahedral coordination geometry with four imidazole N atoms in the equatorial sites and two. The dihedral angles between the central benzene ring and the imidazole rings are 4.93 (11). The 1,3-bis(imidazol-1-yl)-5-methylbenzene ligand is bis-monodentate, linking symmetry-related CuII atoms into sheets in the bc plane. These sheets are further bridged into a three-dimensional supramolecular structure by.
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