Abstract
Reaction of a mixture of AgOAc, Lawesson's reagent [2,4-bis(4-methoxyphenyl)-1,3-dithiadiphosphetane-2,4-disulfide] and 1,3-bis(diphenylphosphanyl)propane (dppp) under ultrasonic treatment gave the title compound, {[Ag(C(9)H(12)O(2)PS(2))(C(27)H(26)P(2))]·CHCl(3)}(n), a novel one-dimensional chain based on the in situ-generated bipodal ligand [ArP(OEt)S(2)](-) (Ar = 4-methoxyphenyl). The compound consists of bidentate bridging 1,3-bis(diphenylphosphanyl)propane (dppp) and in situ-generated bidentate chelating [ArP(OEt)S(2)](-) ligands. The dppp ligand links the [Ag{ArP(OEt)S(2)}] subunit to form an achiral one-dimensional infinite chain. These achiral chains are packed into chiral crystals by virtue of van der Waals interactions. No π-π interactions are observed in the crystal structure.
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