Abstract
Syntheses are reported for trithienylphosphine analogs of hydridocarbonyltris (triphenylphosphine) rhodium(I) and the catalytic activity of these analogs in the hydrogenation and isomerization of terminal olefins was demonstrated. The PMR chemical shifts and form of the signals of the hydride hydrogen atom of these rhodium hydridocarbonyl complexes correlate with their catalytic properties in homogeneous hydrogenation and isomerization.
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