Abstract
Cap in hand: Combined use of diamino-γ-cyclodextrin (CD) and Cu(ClO4)2 resulted in the first catalytic supramolecular photochirogenesis in the photocyclodimerization of 2-anthracenecarboxylic acid. The anti-head-to-head cyclodimer formed in 64–70 % enantiomeric excess and about 50 % yield; these values are the highest ever reported for CD-mediated photochirogenesis. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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