Abstract
The title compound, [Rh(C10H7N2O2)(C18H15P)(CO)]·(CH3)2CO, is the second structural report of a metal complex formed with the O,O′-C10H7N2O2 (neocupferrate) ligand. In the crystal structure, the metal centre is surrounded by one carbonyl ligand, one triphenylphosphine ligand and the bidentate neocupferrate ligand, forming a distorted square-planar RhCO2P coordination set which is best illustrated by the small O—Rh—O bite angle of 77.74 (10)°. There are no classical hydrogen-bond interactions observed for this complex.
Highlights
The title compound, [Rh(C10H7N2O2)(C18H15P)(CO)]Á(CH3)2CO, is the second structural report of a metal complex formed with the O,O0-C10H7N2O2 ligand
The metal centre is surrounded by one carbonyl ligand, one triphenylphosphine ligand and the bidentate neocupferrate ligand, forming a distorted squareplanar RhCO2P coordination set which is best illustrated by the small O—Rh—O bite angle of 77.74 (10)
119.8 119.8 119.6 (4) 120.2 120.2 120.2 (4) 119.9 119.9 120.7 (4) 119.6 119.6 123.7 (3) 118.5 (3) 117.8 (3) 119.3 (4) 120.3 120.3 119.5 (4) 120.2 120.2 121.9 (4) 119.1 119.1 sup-6
Summary
The title compound, [Rh(C10H7N2O2)(C18H15P)(CO)]Á(CH3)2CO, is the second structural report of a metal complex formed with the O,O0-C10H7N2O2 (neocupferrate) ligand. Related literature For synthesis of similar Rh complexes and information on oxidative addition products, see: Basson et al (1984, 1986); Steyn et al (1992); Smit et al (1994); Roodt & Steyn (2000). For another structural report of a complex with the bidentate neocupferrate ligand, see: Tamaki & Okabe (1998).
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