Abstract
AbstractThe 13C NMR chemical shifts of m‐ and p‐substituted benzyl N,N‐dimethylcarbamates were measured in CDCl3. The meta and para 13C substituent chemical shifts were analysed by means of dual substituent parameter (DSP) equations. Good correlations were obtained, especially for the para‐carbon substituent chemical shifts. The computed transmission coefficients, ρI and ρR, are consistent with the general features of the fitting parameters. It has been shown that no significant electron demand is imposed by the CH2OCON(CH3)2 substituent.
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