Abstract

The carbon monoxide content in a purified nitrogen gas is detected by a highly sensitive atmospheric pressure ionization (API) method. Although CO has the same molecular weight as N/sub 2/, its ionization potential is quite different. Most ion species produced from nitrogen disappear when 100 ppM of Kr is added to the sample gas, and only ions relating to CO ((CO)/sub 2//sup +/ and Kr/sup +/CO) can be successfully and selectively detected. Relation curves between CO concentration and (CO)/sub 2//sup +/, as well as Kr/sup +/CO ion intensities are obtained. The concentration of CO included in a purified nitrogen gas is estimated to be 110 ppB. The detection limit of Kr/sup +/CO ions in this system is determined by the interference from Kr/sup +/N/sub 2/ ions and is 15 ppB or less. 5 figures.

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