Abstract
Abstract[K{Al(NONDipp)}]2(NONDipp=[O(SiMe2NDipp)2]2−, Dipp=2,6‐iPr2C6H3) reacts with CS2to afford the trithiocarbonate species [K(OEt2)][Al(NONDipp)(CS3)]1or the ethenetetrathiolate complex, [K{Al(NONDipp)(S2C)}]2[3]2. The dimeric alumoxane [K{Al(NONDipp)(O)}]2reacts with carbon monoxide to afford the oxygen analogue of3, [K{Al(NONDipp)(O2C)}]2[4]2containing the hitherto unknown ethenetetraolate ligand, [C2O4]4−.
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