Abstract

A system of ionic components of \(\bar C_{p,i}^0 \) is proposed for the standard partial molar heat capacities \(\bar C_{p2}^0 \) of electrolytes in a mixed N-methylpyrrolidone (MP)-water solvent. The \(\bar C_{p,i}^0 \) values are calculated for Li+, Na+, K+, Rb+, Cs+, and I− ions in a mixed MP-water solvent at 298.15 K. The individual components of \(\bar C_{p,i}^0 \) values and their dependence on the solvent composition and ion size are considered.

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