Abstract

Mechanical twins are common microstructures in deformed calcite. Calcite twins have been used for a long time as indicators of stress/strain orientations and magnitudes. Developments during the last decade point toward significant improvements of existing techniques as well as new applications of calcite twin analysis in tectonic studies. This review summarises the recent progress in the understanding of twin formation, including nucleation and growth of twins, and discusses the concept of CRSS and its dependence on several factors such as strain, temperature and grain size. Classical and recent calcite twin measurement techniques are also presented and their pros and cons are discussed. The newly proposed inversion techniques allowing for the use of calcite twins as indicators of orientations and/or magnitudes of stress and strain are summarized. Benefits for tectonic studies are illustrated through the presentation of several applications, from the scale of the individual tectonic structure to the continental scale. The classical use of calcite twin morphology (e.g., thickness) as a straightforward geothermometer is critically discussed in the light of recent observations that thick twins do not always reflect deformation temperature above 170–200 °C. This review also presents how the age of twinning events in natural rocks can be constrained while individual twins cannot be dated yet. Finally, the review addresses the recent technical and conceptual progress in calcite twinning paleopiezometry, together with the promising combination of this paleopiezometer with mechanical analysis of fractures or stylolite roughness.

Highlights

  • Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations.Licensee MDPI, Basel, Switzerland.A twin is a planar crystallographic defect that separates two homogeneous parts of a single crystalline species in a symmetric way [1] (Figure 1A–C)

  • Köpping et al [63] reported the use of a fabric analyser to speed up and improve the collection of calcite twin data to be used in further paleostress and paleostrain analyses

  • (1) the understanding of the occurrence of calcite deformation twins, (2) the methodological development of both acquisition and treatment of calcite twins and (3) strain and stress gauge applications. It proposes a critical snapshot of the state of the art, highlighting some new findings partly challenging established concepts, such as paleothermometry based on twin thickness

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Summary

Introduction

Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations. In the classical theory of deformation twinning, the original (parent) lattice is re-orientated by atom displacements which are geometrically equivalent to a simple shear of the lattice (Figure 1C). This paper does not intend at providing a comprehensive review of the state of knowledge about the processes and physical mechanisms behind (calcite) twinning; the reader can refer to the previous review papers on the topic [4,9,10,11] This contribution aims at providing an overview of the progress realized over the past decade on the understanding of the formation of calcite twins, their measurement and their use as tectonic markers and stress-strain gauge in the shallow upper crust

Nucleation and Growth of Twins
The Concept of CRSS for Twinning
Dependence of CRSS on Temperature and Strain Rate
Dependence of CRSS on Strain
Dependence of CRSS on Grain Size
Calcite Twins: A Low-Temperature Geothermometer?
Universal Stage
Automated Fabric Analyser
Calcite Twins
Use of Calcite Twins as Markers of Stress Regime
Etchecopar Technique
Yamaji Technique
Concept
Parlangeau et al Technique
Euler’slie angles the orientation thespace principal
Shan et al Technique
Rez Technique
Some Regional Studies Using Analysis of Calcite Twins for Paleostress
Dating Calcite Twinning Events
Use of Calcite Twins as a Strain Gauge
Use of Calcite Twins as a Stress Gauge
Calcite Twinning Paleopiezometry Based on Both Residual Stress and Plastic
Case Studies
11. Paleostress
10.1. Combining
10.2. Combining
Findings
11. Conclusions

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