Abstract
Rhodium(I)-Komplexe der Form [(PNP)Rh(OR)] (R=H, CH2CF3, C6H5; PNP=2,6-Bis[(di-tert-butylphosphanyl)methyl]pyridin) wurden hergestellt. Die Hydroxid- und Trifluorethoxidkomplexe aktivieren Benzol bei der Thermolyse in [D6]Benzol. [(PNP)Rh(OC6H5)] katalysiert den H/D-Austausch zwischen D2O und Benzol sowie zwischen H2O und [D8]Toluol (siehe Schema), bei dem der Austausch selektiv an den meta- und para-Positionen verläuft.
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