Abstract

A formulation of the boundary profile using the square approximation of the cluster variation method is given in such a way that the local free energy density can be indentified clearly and comparison with Paper I can be made easily. It is pointed out that the formulation in Paper II brings in an approximation at the last stage of the method in Paper I, while the formulation in the present Paper does so at an earlier stage. Comparison of the local free energy density in this paper and that in Paper I leads to the solution of the paradox by concluding that the hump in the free energy curve is not objectionable but has a physical significance in the approximate treatment of the boundary profile.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.